The half-life that keeps growing
A second-order step needs two molecules in the same place at the same instant. As the reactant thins, those meetings get rare fast — so a second-order reaction does not just slow down, it slows down and then slows down again. Integrated, that is : is the concentration left at time , the concentration when the clock read zero, the elapsed seconds, and the rate constant in — different units from every other order, which is the giveaway when a question refuses to say which order it is.
Work it as a straight line and it is easy: starts at and climbs by each second. Then — and this is where the marks go — flip it back. The law hands you the RECIPROCAL of the concentration; an answer of 20 is not 20 mol/L, it is 0.05 mol/L wearing its reciprocal upside down.
Now the contrast worth memorising. Ask this law when half is gone and refuses to cancel: — half-life in seconds, in , and the STARTING concentration, genuinely in the answer. Start with less and the half-life is longer. Worse: after one half-life the concentration IS halved, so the next half-life is twice as long, and the one after that twice again. First order's clock ticks evenly forever; second order's clock stretches as you watch it.