Grade 12 Chemistry · The burette
The equivalence point
score 0

The equivalence point

A titration measures a concentration you cannot see by reacting it away against one you can. A pipetted aliquot of the unknown acid waits in the flask; standard base drips from the burette until the indicator turns. At the equivalence point the moles have exactly annihilated, and CaVa=nCbVbC_a V_a = n\,C_b V_b — read aloud: C-a V-a equals n C-b V-b. Every symbol: CaC_a is the analyte's concentration in mol/L (the unknown), VaV_a the aliquot volume, CbC_b the titrant's concentration off the bottle, VbV_b the titre the burette delivered, and nn the mole ratio — moles of ANALYTE per mole of titrant, a pure number. Subscript a is the flask, subscript b is the burette; that convention never changes.

The mole ratio is where marks are lost. HCl against NaOH is one-to-one, so n=1n = 1. Sulfuric acid carries two protons, so one mole of acid spends two of base and n=0.5n = 0.5 — acid per base, and the fraction feels backwards until you say the sentence out loud. One more discipline: because VaV_a and VbV_b meet as a ratio, millilitres cancel and nobody converts. The instant a question asks for moles, that immunity ends — mol/L only cancels against litres, and the ÷1000 becomes compulsory.