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Lesson 24 · Weak acids and ICE
The x that is small enough to ignore
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The x that is small enough to ignore

Put a weak acid in water and set up an ICE table — Initial, Change, Equilibrium. Call the formal concentration CC: the amount you actually made up, in mol/L, before any proton moved. Call xx the concentration that ionizes, in mol/L, which is also the equilibrium [H+][\mathrm{H^+}], since each molecule that lets go releases exactly one proton. Then Ka=x2C−xK_a = \dfrac{x^2}{C - x} — products over reactants, straight off the ICE table's bottom row.

Here is the move that makes it examinable. A weak acid ionizes barely at all, so xx is tiny beside CC, and C−x≈CC - x \approx C. That collapses the algebra to x=KaCx = \sqrt{K_a C}, and therefore pH=−12log⁡(KaC)\mathrm{pH} = -\tfrac{1}{2}\log(K_a C) — read aloud: pH equals minus a half log of K-a C. The half IS the square root, and forgetting it doubles your pH, the single most-marked slip in this unit. Check the approximation afterwards with the percent ionization, % ion=[H+]C×100%\%\,\mathrm{ion} = \dfrac{[\mathrm{H^+}]}{C} \times 100\%: under 5 %, the shortcut was honest; over it, go back and solve the quadratic properly.

CKapH

pH=−log⁡10Ka C\mathrm{pH} = -\log_{10}\sqrt{K_a\,C}

  • pH\mathrm{pH}= pH of the solution
  • KaK_a= Acid dissociation constant
  • CC= Formal acid concentration (molar concentration)
pH of a Weak Acid from Ka solver →
C[H+]% ion

% ion=[H+]C×100%\%\,\text{ion} = \frac{[\mathrm{H^+}]}{C} \times 100\%

  • % ion\%\,\text{ion}= Percent ionization (concentration)
  • [H+][\mathrm{H^+}]= Hydrogen ion concentration at equilibrium (molar concentration)
  • CC= Formal acid concentration (molar concentration)
Percent Ionization of a Weak Acid solver →