The x that is small enough to ignore
Put a weak acid in water and set up an ICE table — Initial, Change, Equilibrium. Call the formal concentration : the amount you actually made up, in mol/L, before any proton moved. Call the concentration that ionizes, in mol/L, which is also the equilibrium , since each molecule that lets go releases exactly one proton. Then — products over reactants, straight off the ICE table's bottom row.
Here is the move that makes it examinable. A weak acid ionizes barely at all, so is tiny beside , and . That collapses the algebra to , and therefore — read aloud: pH equals minus a half log of K-a C. The half IS the square root, and forgetting it doubles your pH, the single most-marked slip in this unit. Check the approximation afterwards with the percent ionization, : under 5 %, the shortcut was honest; over it, go back and solve the quadratic properly.
- = pH of the solution
- = Acid dissociation constant
- = Formal acid concentration (molar concentration)
- = Percent ionization (concentration)
- = Hydrogen ion concentration at equilibrium (molar concentration)
- = Formal acid concentration (molar concentration)