Moles do not evaporate
Concentration is bookkeeping: — read aloud C equals n over V — where is the molar concentration in mol/L, is the amount of solute in moles, and is the volume of the finished solution in litres. Not the volume of solvent you poured: the volume of what is in the flask when you stop.
Now add water. The solute does not care — no moles arrive, none leave — so is conserved while grows, and before must equal after: , read aloud C-one V-one equals C-two V-two. State the subscript convention once and never wobble: 1 is BEFORE the water — the stock you pipetted — and 2 is AFTER — the finished solution. Because the two volumes meet as a ratio, millilitres cancel millilitres and nothing needs converting.
The trap this lesson exists to prevent: is the final total volume, not the water added. Dilute 50 mL up to 300 mL and you added 250 mL of water, not 300. Read the ask twice — one word decides which number gets the mark.