Grade 12 Chemistry · Partial pressures
Every gas thinks it is alone
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Every gas thinks it is alone

Ideal gas molecules ignore each other. Put two gases in one vessel and each behaves exactly as if it owned the place, so the pressures simply add — that is Dalton's law of partial pressures. The practical form is Pi=xiPtotalP_i = x_i\,P_{\text{total}}, read aloud P-sub-i equals x-sub-i times P-total. The subscript ii means “whichever component you are asking about”: PiP_i is that component's partial pressure in kPa, PtotalP_{\text{total}} is what the gauge on the vessel reads, and xix_i is that component's mole fraction.

The mole fraction is built first: x1=n1n1+n2x_1 = \dfrac{n_1}{n_1 + n_2}, where n1n_1 is the amount of the component you want in moles and n2n_2 is the amount of everything else. Subscripts 1 and 2 here name the two COMPONENTS, not a before and an after — this is the one place in the chapter where they do. Moles over moles, so xx carries no unit at all, sits between 0 and 1, and all the mole fractions in a mixture add to exactly 1. That nakedness is what lets it multiply a pressure and hand the kilopascals straight back.

Read it backwards and it is a measurement: a probe reporting a partial pressure is reporting a composition. That is how a blood-gas analyser and a stack monitor both earn their keep — and why dry air's 21 % oxygen shows up as about 21 kPa of the 101 kPa pressing on you right now.