Process & Water Chemistry · Cathodic protection
Three questions, and they must be answered in order
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Three questions, and they must be answered in order

Cathodic protection makes the whole of a structure a cathode by supplying it with electrons from somewhere else — a metal that is willing to corrode instead. Designing it is three questions in a fixed order: how much current does the structure need, can the anodes deliver it, and is there enough anode metal to keep delivering it for the design life.

The demand. I=AifI = A\,i\,fI equals A i f. II is the total protection current in amps. AA is the structure's whole surface area in m² — the cathode, coated or not. ii is the protection current density the environment demands, in mA per square metre of BARE steel: roughly 10 to 30 in soil, 20 to 100 in seawater. ff is the coating breakdown factor, the fraction of the surface actually through to metal — 1 for uncoated steel, a few percent for a good new coating. The whole reason a coating is worth money is that it multiplies this current by a small number.

The output. I=ΔERI = \dfrac{\Delta E}{R}I equals delta-E over R. Here II is the current one anode delivers, ΔE\Delta E is the NET driving voltage — the anode's operating potential less the potential the structure has already polarised to — and RR is the total circuit resistance in ohms: anode-to-earth, plus cable, plus the structure's own resistance to earth. That word NET is where the money is. Once buried steel is polarised to the conventional −0.85 V criterion, zinc has only about 0.2 V of drive left and magnesium about 0.7 V. That difference is the entire reason magnesium is used in high-resistivity soil and zinc is not.

The metal. W=ItCuW = \dfrac{I\,t}{C\,u}W equals I t, over C u. WW is the net anode mass in kg. II is the MEAN current over the life — not the initial and not the final, because a coating breaks down and those are three different numbers. tt is the design life, and the capacity below is quoted in amp-HOURS, so the years have to arrive as hours: take the year as 8766. CC is the alloy's practical current capacity in A·h/kg — zinc 780, magnesium 1100, aluminium 2500. uu is the utilisation factor, the fraction of the anode that can actually be consumed before the metal near the core insert loses contact and falls off: 0.90 for slender stand-off shapes, 0.80 for bracelets.

Both denominators are where optimism costs a system its life. Note that the practical capacities above are already below the theoretical ones Faraday's law gives — 820 for zinc, 2980 for aluminium, 2200 for magnesium — because current efficiency is never 100 %. And the nugget: an anode that lasts is not the same as an anode that works. Mass answers the life question; the voltage over the resistance answers the output question, and a system can pass one and fail the other on the same day.