Process & Water Chemistry · Gases in the vessel
Four variables, one referee
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Four variables, one referee

PV=nRTPV = nRT, read aloud P V equals n R T. PP is the absolute pressure in pascals — absolute, not gauge, because a gas at zero gauge still has atmosphere in it. VV is the volume in cubic metres, nn the amount of gas in moles, TT the absolute temperature in kelvin, and RR the molar gas constant, 8.314 J/(mol·K).

RR is the referee, and it only whistles in one set of units. There is a check that never fails: multiply your pressure unit by your volume unit and ask whether the answer is a joule. Pa·m³ is. kPa·L is. bar·m³ is a hundred thousand of them. And the resident trap of every gas problem is the temperature: RR is per kelvin, so 27 °C goes in as 300.15 K. Celsius fed into a gas law does not give a slightly wrong answer; at low temperatures it gives an absurd one, and at 0 °C it divides by zero.

At STP — 0 °C and 101.325 kPa — the whole of RT/PR T / P has already been worked out and given a name: the molar volume VmV_m, 22.414 L/mol, which every exam paper prints as 22.4. Then V=nVmV = n\,V_m, V equals n times V-m. The remarkable part is that VmV_m is the same for every ideal gas: chlorine, ammonia, oxygen — one mole, one bucketful, whatever the molecule weighs. The fine print is the reference condition. Off STP the shortcut's contract is void, and 25 °C has its own molar volume of 24.5 L/mol, which is a perfectly good number quoted at the wrong temperature.

Density needs no new physics. Put n=m/Mn = m/M into the gas law, divide through by VV, and ρ=PMRT\rho = \dfrac{PM}{RT} falls out — rho equals P M over R T — where ρ\rho (rho) is the density in kg/m³ and MM the molar mass, in kilograms per mole for SI to balance. Read its shape: at one pressure and temperature, density is simply proportional to molar mass.

That last line is a safety fact before it is a chemistry one. Chlorine at 71 g/mol is two and a half times as dense as air and pools in pits, trenches and sumps. Ammonia at 17 g/mol is lighter than air and goes for the ceiling. Where you put the detector follows directly from an equation you can write in eight characters.