Equivalent Weight of Hydrochloric Acid

EW(HCl)=0.036458 kg/mol\mathrm{EW}(\mathrm{HCl}) = 0.036458\ \text{kg/mol}
Value0.036458 kg/mol
StatusMeasured: ± 0.00001 kg/mol (0.00027 relative)
SourceIUPAC
CategoriesChemistryequivalent-weightwater-treatment
Equivalent Weight of Hydrochloric Acid in every molar mass unit
gram per mole36.458 g/mol
kilogram per kilomole36.458 kg/kmol
milligram per millimole36.458 mg/mmol
pound per pound-mole36.458 lb/lb-mol
dalton (as molar mass)36.458 Da
kilogram per mole0.036458 kg/mol
kilodalton (as molar mass)0.036458 kDa

Learning zone

Hydrochloric acid is monoprotic, so there is no division to do: 1.008 + 35.45 = 36.458 g/mol, and one proton per molecule makes the equivalent weight the same number. Each 36.458 g of pure HCl removes one equivalent of alkalinity — 50.04 g as CaCO₃ — so gram for gram it hits about 37 % harder than sulfuric acid. What arrives on site is never pure: muriatic acid, the commercial grade, is typically 31.45 % HCl (20 °Baumé), and the acid-feed solver's strength input exists exactly for that correction.

Hydrochloric earns its place where sulfate is unwelcome — ahead of a reverse-osmosis membrane running near the gypsum limit, or in a closed loop where added sulfate would feed sulfate-reducing bacteria. Its own baggage is chloride: every equivalent fed adds a chloride ion, and chloride is the numerator of the Larson–Skold index, the aggressive species that pits mild steel. The choice between the two workhorse acids is usually a choice about which anion the system can better afford to accumulate.