Equivalent Weight of Sodium Bisulfate

EW(NaHSO4)=0.120054 kg/mol\mathrm{EW}(\mathrm{NaHSO_4}) = 0.120054\ \text{kg/mol}
Value0.120054 kg/mol
StatusMeasured: ± 0.00002 kg/mol (0.00017 relative)
SourceIUPAC
CategoriesChemistryequivalent-weightwater-treatment
Equivalent Weight of Sodium Bisulfate in every molar mass unit
gram per mole120.054 g/mol
kilogram per kilomole120.054 kg/kmol
milligram per millimole120.054 mg/mmol
pound per pound-mole120.054 lb/lb-mol
dalton (as molar mass)120.054 Da
kilogram per mole0.120054 kg/mol
kilodalton (as molar mass)0.120054 kDa

Learning zone

Sodium bisulfate is what remains after sulfuric acid has spent one of its two protons on caustic soda, and the proton it keeps is still a strong one — HSO₄⁻ has a pKa of about 1.99, so it titrates completely against alkalinity. One proton per formula unit makes the equivalent weight the whole formula mass: 22.990 + 1.008 + 32.06 + 4 × 15.999 = 120.054 g/eq. That is 2.4 times sulfuric acid's 49.036, which is the price of the convenience — you haul, store and dissolve two and a half times the product mass for the same alkalinity knocked out.

The convenience is real, though: a dry granular solid with no fume, no drum of concentrated acid, and a spill you sweep up rather than neutralise. It is sold as "dry acid" for pools and spas and as pH-down granules for a dozen small-system uses, and it is often the only acid a site without proper chemical containment should be handling. The anion story matches its parent acid — every equivalent adds sulfate — and supplier sheets that print 120.06 g/mol are carrying a rounding from the older sulfur atomic weight; the IUPAC 2021 arithmetic gives 120.05.