Water Treatment constants

20 values, each with its units, its uncertainty, and where it came from.

Equivalent Weight of Citric Acid measured

EW(C6H8O7)=0.064041 kg/mol\mathrm{EW}(\mathrm{C_6H_8O_7}) = 0.064041\ \text{kg/mol}

kg/molThe equivalent weight of citric acid, 64.041 g/eq — a third of the 192.123 g/mol molar mass, counting all three carboxylic protons.

Equivalent Weight of Hydrated Lime measured

EW(Ca(OH)2)=0.037046 kg/mol\mathrm{EW}(\mathrm{Ca(OH)_2}) = 0.037046\ \text{kg/mol}

kg/molThe equivalent weight of hydrated lime, 37.046 g/eq — half of Ca(OH)₂'s 74.092 g/mol, two hydroxides per formula unit of slaked lime.

Equivalent Weight of Hydrochloric Acid measured

EW(HCl)=0.036458 kg/mol\mathrm{EW}(\mathrm{HCl}) = 0.036458\ \text{kg/mol}

kg/molThe equivalent weight of hydrochloric acid, 36.458 g/eq — equal to its molar mass, since the molecule has exactly one proton to give.

Equivalent Weight of Nitric Acid measured

EW(HNO3)=0.063012 kg/mol\mathrm{EW}(\mathrm{HNO_3}) = 0.063012\ \text{kg/mol}

kg/molThe equivalent weight of nitric acid, 63.012 g/eq — identical to the molar mass because HNO₃ is monoprotic, one proton per molecule.

Equivalent Weight of Phosphoric Acid measured

EW(H3PO4)=0.097994 kg/mol\mathrm{EW}(\mathrm{H_3PO_4}) = 0.097994\ \text{kg/mol}

kg/molThe equivalent weight of phosphoric acid for alkalinity work, 97.994 g/eq — one proton counted, since only the first titrates by pH 4.5.

Equivalent Weight of Soda Ash measured

EW(Na2CO3)=0.052994 kg/mol\mathrm{EW}(\mathrm{Na_2CO_3}) = 0.052994\ \text{kg/mol}

kg/molThe equivalent weight of soda ash, 52.994 g/eq — half of Na₂CO₃'s 105.988 g/mol, since carbonate accepts two protons on the way to CO₂.

Equivalent Weight of Sodium Bicarbonate measured

EW(NaHCO3)=0.084006 kg/mol\mathrm{EW}(\mathrm{NaHCO_3}) = 0.084006\ \text{kg/mol}

kg/molThe equivalent weight of sodium bicarbonate, 84.006 g/eq — the whole formula mass, one proton accepted, the gentlest alkalinity feed.

Equivalent Weight of Sodium Bisulfate measured

EW(NaHSO4)=0.120054 kg/mol\mathrm{EW}(\mathrm{NaHSO_4}) = 0.120054\ \text{kg/mol}

kg/molThe equivalent weight of sodium bisulfate, 120.054 g/eq — the full formula mass, one acidic proton, the workhorse of dry acid dosing.

Equivalent Weight of Sulfuric Acid measured

EW(H2SO4)=0.049036 kg/mol\mathrm{EW}(\mathrm{H_2SO_4}) = 0.049036\ \text{kg/mol}

kg/molThe equivalent weight of sulfuric acid, 49.036 g/eq — half the 98.072 g/mol molar mass, because each H₂SO₄ delivers two protons.

First pKₐ of Carbonic Acid measured

pKa1(H2CO3)=6.352\mathrm{p}K_{\mathrm{a1}}(\mathrm{H_2CO_3}) = 6.352

dimensionlessThe first pKₐ of carbonic acid at 25 °C, 6.352 — the pH at which dissolved CO₂ and bicarbonate are present in equal concentrations.

Second pKₐ of Carbonic Acid measured

pKa2(H2CO3)=10.329\mathrm{p}K_{\mathrm{a2}}(\mathrm{H_2CO_3}) = 10.329

dimensionlessThe second pKₐ of carbonic acid at 25 °C, 10.329 — the pH at which bicarbonate and carbonate ions are present in equal concentrations.

Solubility Product of Calcium Carbonate measured

Ksp(CaCO3)=3.36×10−9K_{\mathrm{sp}}(\mathrm{CaCO_3}) = 3.36 \times 10^{-9}

dimensionlessThe solubility product of calcite at 25 °C, K_sp = 3.36 × 10⁻⁹ — the number that decides whether a water scales or corrodes.

Solubility Product of Calcium Sulfate measured

Ksp(CaSO4)=0.0000493K_{\mathrm{sp}}(\mathrm{CaSO_4}) = 0.0000493

dimensionlessThe solubility product of anhydrous calcium sulfate at 25 °C, K_sp = 4.93 × 10⁻⁵ — the gypsum scale that acid cleaning cannot remove.