Heat capacity ratio of argon

γAr=1.667 —\gamma_{\mathrm{Ar}} = 1.667\ \text{—}
Value1.667 —
StatusReference value; the source states no uncertainty
SourceKinetic theory for a monatomic gas, 5/3; the Tegeler, Span and Wagner (1999) equation of state for argon, computed with CoolProp, gives 1.670 at 20 °C and 1 atm
CategoriesThermodynamicChemistry
Heat capacity ratio of argon in every dimensionless unit
UnitValue
ratio1.667 —
percent166.7 %
part per trillion1,667,000,000,000 ppt
part per billion1,667,000,000 ppb
part per million1,667,000 ppm
per cent mille166,700 pcm
basis point16,670 bp
per mille1,667 per mille

Learning zone

A monatomic gas stores energy only in translation (three degrees of freedom, no rotation or vibration to speak of) so cv = (3/2)R, cp = (5/2)R and γ = 5/3 = 1.6667. Argon, helium, neon, krypton and xenon all measure within a fraction of a percent of it over enormous temperature ranges, which is about as clean as physics gets.

That reliability is why argon is the working gas of choice for acoustic thermometry, the technique that measured the Boltzmann constant precisely enough to redefine the kelvin in 2019: with γ known exactly from theory, the speed of sound in argon gives kT/m directly. The high γ is also why helium and argon heat up so much in adiabatic compression, and why helium-oxygen mixes change a diver's voice.

Revised 1 November 2026
Cite this page

formula.expert. (2026, November 1). Heat capacity ratio of argon. https://formula.expert/constants/heat-capacity-ratio-argon