Maximum density of water (4 °C)

ρmax=999.975 kg/m3\rho_{\max} = 999.975\ \text{kg/m}^{3}
Value999.975 kg/m³
StatusMeasured: ± 0.001 kg/m³ (0.000001 relative)
SourceTanaka et al. (2001), CIPM-recommended formula for VSMOW
CategoriesThermodynamicMaterial Properties
ρ_max in every density unit
kilogram per cubic meter999.975 kg/m³
gram per cubic centimeter0.999975 g/cm³
gram per milliliter0.999975 g/mL
kilogram per liter0.999975 kg/L
pound per cubic foot62.4264 lb/ft³
pound per US gallon8.3451958 lb/gal

Learning zone

Almost every liquid gets denser as it cools, right down to freezing. Water reverses near 3.98 °C: below that, hydrogen bonds start assembling the open tetrahedral structure of ice, and the liquid expands again. The peak density is 999.975 kg/m³ — the reason the kilogram was originally meant to be the mass of a litre of water, and the reason that definition was so nearly right.

The consequence is ecological. As a lake cools in autumn the surface water sinks until the whole body reaches 4 °C; colder water is then lighter and stays on top, freezing into a floating lid that insulates everything beneath. Lakes freeze from the top down, not the bottom up, and fish survive the winter. Ice itself is 917 kg/m³, about 8 % less dense than liquid water, which is why it floats and why frozen pipes burst.