Relative permittivity of water

εr,H2O=80.1 —\varepsilon_{r,\mathrm{H_2O}} = 80.1\ \text{—}
Value80.1 —
StatusMeasured: ± 0.5 — (0.0062 relative)
SourceCRC Handbook — typical value, liquid water at 20 °C, static field
CategoriesElectromagneticMaterial PropertiesChemistry
epsilon_r,water in every dimensionless unit
ratio80.1
percent8,010 %

Learning zone

Water's static dielectric constant of about 80 is enormous for a small molecule. It comes from the permanent dipole of the bent H–O–H geometry combined with hydrogen bonding, which lets whole clusters reorient together in an applied field. The practical consequence is Coulomb's law divided by 80: the electrostatic attraction holding Na⁺ to Cl⁻ drops eightyfold when the pair is surrounded by water, which is why table salt dissolves and why water is the universal solvent of biology.

The value is strongly temperature-dependent — about 87.9 at 0 °C, 80.1 at 20 °C, 78.4 at 25 °C and 55.6 at 100 °C — because heat disrupts the hydrogen-bond network that makes cooperative alignment possible. It is also frequency-dependent: above roughly 20 GHz the molecules can no longer follow the field, and the resulting dielectric loss is precisely what heats food in a microwave oven. Treat any single figure here as a typical value tied to its temperature.