Standard state pressure

p∘=100,000 Pap^{\circ} = 100,000\ \text{Pa}
Value100,000 Pa
StatusExact by definition — no uncertainty
SourceIUPAC (1982); SI Brochure, 9th edition
CategoriesThermodynamicChemistry
Standard state pressure in every pressure unit
microbar1,000,000 μbar
barye1,000,000 Ba
millitorr750,061.68 mTorr
pascal100,000 Pa
millimeter of water column10,197.162 mmH₂O
pound per square foot2,088.5434 lb/ft²
centimeter of water column1,019.7162 cmH₂O
hectopascal1,000 hPa
millibar1,000 mbar
torr750.06168 Torr
millimeter of mercury750.06158 mmHg
inch of water column401.46308 in w.g.
kilopascal100 kPa
foot of water column33.455257 ft H₂O
inch of mercury29.529983 inHg
pound per square inch14.503774 psi
meter of water column10.197162 m H₂O
decibar10 dbar
kilogram-force per square centimeter1.0197162 kgf/cm²
bar1 bar
atmosphere0.98692327 atm
megapascal0.1 MPa
kip per square inch0.014503774 ksi
gigapascal0.0001 GPa
million pounds per square inch0.000014503774 Mpsi

Learning zone

Every standard enthalpy of formation, standard entropy and equilibrium constant is quoted relative to a reference pressure, and since 1982 IUPAC's is exactly 1 bar = 100 000 Pa. The superscript degree symbol in ΔG° means "at p° = 1 bar", and the partial pressures inside an equilibrium constant are divided by it — which is why K is dimensionless.

Older tables use 1 atm = 101.325 kPa, a 1.3 % difference. For most reactions it shifts ΔG° by only tens of joules per mole, but it changes tabulated standard entropies of gases by R ln(1.01325) ≈ 0.109 J/(mol·K), enough to matter in precise work. Standard state fixes pressure only; the temperature is whatever the table says, conventionally 298.15 K.