The mole, reactions, solutions, gases, water and pH

Grade 11 Chemistry

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The Mole

  • L1
    Lesson 1
    Counting by weighing
    Which number is which: mass, molar mass, amount

    Chemistry happens one particle at a time — this atom meets that one — and particles are far too small to count. So chemists count the only way anyone can: they WEIGH.

  • L2
    Lesson 2
    Moles from mass
    The chemist's headcount

    If apples cost 2 dollars each and you spent 18 dollars, you bought 9 apples: you divided the total by the price of one. Molar mass is the price of one mole, in grams.

    The formula in this lesson
    n=mMn = \dfrac{m}{M}
  • L3
    Lesson 3
    Mass and molar mass
    n = m/M rearranged · name the unknown by its M

    Solve it for the mass and you get m = nM — the recipe question, how much do I weigh out?

  • L4
    Lesson 4
    Counting particles
    Avogadro's enormous number

    Read the subscript aloud as “N sub A”; the A is for Avogadro, who never measured it and has it named after him anyway, which is science being generous.

    The formula in this lesson
    N=n NAN = n \, N_A
  • L5
    Lesson 5
    Percent composition
    How much of the compound is this element

    Weigh the X atoms in ONE formula unit, divide by what that whole formula unit weighs, and multiply by a hundred. Notice it needs no sample at all — a speck of water and a lake of water are both 11.1 % hydrogen by mass.

    The formula in this lesson
    %X=a MXMcompound×100%\%X = \dfrac{a\,M_X}{M_{\text{compound}}} \times 100\%
  • L6
    Lesson 6
    The mole two-step
    grams → moles → particles · answers chain

    Here is the map of this whole chapter, and it is worth memorising as a picture: grams ⇄ moles ⇄ particles.

    The formulas in this lesson
    N=n NAN = n \, N_A,n=mMn = \dfrac{m}{M}
  • ★
    Boss lesson
    The Mole Inspection
    the boss · no calculator · one sample, every question

    One sample, one long problem, and every answer feeds the next: build the molar mass from the atoms, weigh out the moles, hand them to Avogadro, then say what share of the mass one element carries.

    The formula in this lesson
    n=mMn = \dfrac{m}{M}

Reactions by the Numbers

  • L8
    Lesson 8
    Paper versus flask
    actual, theoretical, percent — the three tells

    Every synthesis has two endings. On paper, stoichiometry works out a maximum — the theoretical yield, a prediction computed before the flask is even dirty.

  • L9
    Lesson 9
    Percent yield
    actual over theoretical, times one hundred

    Keep the flask's number on TOP. Both entries are masses of the same product, so the grams cancel completely: a percent yield is a pure number, and it travels without units, like the coefficients of friction do in physics.

    The formula in this lesson
    % yield=mamt×100\%\,\text{yield} = \dfrac{m_a}{m_t} \times 100
  • L10
    Lesson 10
    Working back from yield
    given the yield, recover the mass

    The yield formula runs backwards as happily as forwards. Know the promise and the yield?

  • L11
    Lesson 11
    Heat of reaction
    Moles carry the heat

    At this rung the words in the question already say which way the heat flows, so compute with magnitudes and let “released” or “absorbed” speak the sign.

    The formula in this lesson
    q=n ΔHq = n\,\Delta H
  • L12
    Lesson 12
    Moles to heat
    grams → moles → kilojoules

    Grams → moles → kilojoules: two small formulas, one chain, and the mole count is the coupling between them.

    The formulas in this lesson
    n=mMn = \dfrac{m}{M},q=n ΔHq = n\,\Delta H
  • L13
    Lesson 13
    Estimate, then compute
    land the power of ten before the calculator

    Before any calculator, run the one-digit version: round every value to a single digit, multiply or divide in your head, and count the zeros. 3.9 of 5.2 grams?

  • ★
    Boss lesson
    The Lab Report
    the boss · no calculator · mass to heat to yield

    No calculator — the masses land on clean multiples of the molar mass, the enthalpies are round, and the percents are the friendly kind.

    The formula in this lesson
    n=mMn = \dfrac{m}{M}

Solutions & Dilution

  • L15
    Lesson 15
    Reading the label
    mol/L, percent, grams — which concentration is which

    Chemists nickname it molarity, and a 2 mol/L bottle gets called “two molar” — written 2 M for short. The slash is the tell. mol/L divides a mole count by a volume — that is molarity.

  • L16
    Lesson 16
    Molarity
    Moles per litre of solution

    Twice the solute in the same flask, twice the concentration; the same solute in twice the water, half. The unit mol/L says exactly what the formula does — moles upstairs, litres downstairs.

    The formula in this lesson
    C=nVC = \dfrac{n}{V}
  • L17
    Lesson 17
    Molarity, every way
    C = n/V rotated · find n, find V, find C

    Solved for the moles it reads n = C V — how much solute a measured pour actually carries.

  • L18
    Lesson 18
    Mass percent
    solute over solution — not over solvent

    That is the whole trap of this lesson, so hear it twice: the solute is PART of the solution it sits in. The denominator is solute plus solvent, added before anything is divided.

    The formula in this lesson
    c=msmt×100%c = \dfrac{m_s}{m_t} \times 100\%
  • L19
    Lesson 19
    Dilution
    The moles never left

    Add water to a solution and one thing refuses to change: the moles of solute. Water brings volume and nothing else — every particle that was in the flask is still in the flask.

    The formula in this lesson
    C1V1=C2V2C_1 V_1 = C_2 V_2
  • L20
    Lesson 20
    Dilution, every way
    C₁V₁ = C₂V₂ rotated · water to add is V₂ − V₁

    Keep the subscripts honest — 1 is the strong start, 2 is the watery finish — and every rearrangement is one division away.

  • L21
    Lesson 21
    Stockroom chains
    grams → moles → molarity → dilution

    Nothing on a stockroom shelf was born a solution.

    The formulas in this lesson
    n=mMn = \dfrac{m}{M},C1V1=C2V2C_1 V_1 = C_2 V_2
  • ★
    Boss lesson
    The Stockroom
    the boss · no calculator · one stock bottle, three jobs

    No calculator — the molar mass is a friendly 40 g/mol, the concentrations land on 0.1, 0.5, 1 and 2 mol/L, and every draw fits in your head.

    The formula in this lesson
    n=mMn = \dfrac{m}{M}

Gases

  • L23
    Lesson 23
    The gas variables
    P, V, T, n — and why T must be kelvin

    Every gas problem in this chapter turns the same four dials: pressure P in kilopascals (the gas drumming on its container), volume V in litres (the room it fills), temperature T (how hard the particles jiggle), and amount n in moles (the…

  • L24
    Lesson 24
    Boyle's law
    Squeeze it and it pushes back

    Trap some gas, hold its temperature steady, and squeeze: the volume drops, the pressure climbs, and their PRODUCT never moves.

    The formula in this lesson
    P1V1=P2V2P_1 V_1 = P_2 V_2
  • L25
    Lesson 25
    Hot gases
    Charles and Gay-Lussac · kelvin or bust

    One question sorts every problem: can it swell? Free to swell is Charles; locked rigid is Gay-Lussac. And here the kelvin doctrine collects.

    The formulas in this lesson
    V1T1=V2T2\dfrac{V_1}{T_1} = \dfrac{V_2}{T_2},P1T1=P2T2\dfrac{P_1}{T_1} = \dfrac{P_2}{T_2}
  • L26
    Lesson 26
    The combined gas law
    P₁V₁/T₁ = P₂V₂/T₂ · one law, six knobs

    Real gases rarely change one thing at a time. A balloon that climbs meets thinner air AND colder air together.

  • L27
    Lesson 27
    The ideal gas law
    R makes the units agree

    The ratio laws compare a gas to ITSELF, before and after. The ideal gas law needs no before: PV = nRT — P V equals n R T — pins down a single state, because it knows something the ratios never asked: how MUCH gas is there.

    The formula in this lesson
    PV=nRTPV = nRT
  • L28
    Lesson 28
    PV = nRT, every way
    rotated unknowns · real lab conditions

    PV = nRT is one fact wearing four outfits: solve it for P, V, n or T and it answers four different exam questions. Solved for n it is a gas COUNTER — the stockroom's way of auditing a cylinder without opening it.

  • L29
    Lesson 29
    Molar volume at STP
    22.4 L per mole · the shortcut and its fine print

    Helium, oxygen, carbon dioxide — same rent, because ideal gas particles are all equally standoffish regardless of their size.

    The formulas in this lesson
    V=n VmV = n\,V_m,PV=nRTPV = nRT
  • L30
    Lesson 30
    Weighing a gas
    ρ = PM/RT · why helium floats

    Gases have weight — a litre of the air around you carries about 1.2 g.

  • ★
    Boss lesson
    The Pressure Test
    the boss · no calculator · one balloon, launch to altitude

    One balloon, launch to altitude, and every answer feeds the next: count the moles at the fill, then ride the combined law up — pressure's stretch first, the chill's cut second.

    The formulas in this lesson
    V=n VmV = n\,V_m,P1V1T1=P2V2T2\dfrac{P_1 V_1}{T_1} = \dfrac{P_2 V_2}{T_2}

Water by the Numbers

  • L32
    Lesson 32
    Parts per million
    mg/L is ppm in water · reading a water report

    A litre of water weighs a kilogram — a thousand grams, a million milligrams. So one milligram dissolved in one litre is one part in a million: 1 mg/L = 1 ppm — read aloud: one milligram per litre IS one part per million.

  • L33
    Lesson 33
    Hard water
    total hardness as CaCO₃ · calcium plus magnesium

    Hardness is dissolved calcium and magnesium — the pair behind kettle scale and stubborn soap scum. The trade reports both in a single currency, mg/L as CaCO₃: as if every hardness ion were chalk.

    The formula in this lesson
    TH=2.497 Ca+4.118 Mg\mathrm{TH} = 2.497\,\mathrm{Ca} + 4.118\,\mathrm{Mg}
  • L34
    Lesson 34
    Grains per gallon
    the softener dial's unit · the ÷17.118 crossing

    The grain is 64.8 mg — the mass of a barley seed, one of the oldest units still drawing a paycheque. Water-softener dials across North America speak grains of hardness per US gallon, while every lab report speaks mg/L as CaCO₃.

  • L35
    Lesson 35
    The CaCO₃ yardstick
    equivalent weight · why every ion gets measured in chalk

    Calcium carbonate's is the trade's favourite number: M = 100.09 g/mol, z = 2, so EW = 50.04 — almost a round fifty. That near-roundness is exactly WHY chalk got elected the yardstick.

    The formulas in this lesson
    EW=Mz\mathrm{EW} = \dfrac{M}{z},CCaCO3=C⋅50.04EWC_{\mathrm{CaCO_3}} = C \cdot \dfrac{50.04}{\mathrm{EW}}
  • L36
    Lesson 36
    TDS from conductivity
    The meter measures salt indirectly

    Pure water barely conducts; dissolved ions carry the current.

    The formula in this lesson
    TDS=k⋅EC\mathrm{TDS} = k \cdot \mathrm{EC}
  • L37
    Lesson 37
    Chlorine dose
    What the water eats first

    Feed chlorine to raw water and the water eats first: iron, manganese, organics and ammonia consume their share before any protection is left over.

    The formula in this lesson
    dose=demand+residual\text{dose} = \text{demand} + \text{residual}
  • L38
    Lesson 38
    Feeding the plant
    lb/day = mg/L × MGD × 8.34 · the operator's constant

    MGD is million US gallons per day, the flow unit of the trade, and 8.34 is what one gallon of water weighs in pounds.

  • ★
    Boss lesson
    The Treatment Plant
    the boss · no calculator · one raw-water sample, start to finish

    No calculator — today the hardness factors round to 2.5 and 4, the k values arrive clean, and every number is chosen to fit in your head.

    The formula in this lesson
    TDS=k⋅EC\mathrm{TDS} = k \cdot \mathrm{EC}

Acids, Bases & pH

  • L40
    Lesson 40
    The pH scale
    acidic, basic, neutral — and what pH measures

    What the compression buys is a ruler that runs about 0 to 14: 7 is neutral (pure water, room temperature), below 7 is acidic — the lower, the fiercer — and above 7 is basic.

  • L41
    Lesson 41
    pH from concentration
    The exponent, flipped positive

    The resident trap is that minus sign. Forget it and pH 3 becomes −3, which would out-acid anything in a school stockroom — if your pH comes out negative on this paper, the sign slipped; go back one line.

    The formula in this lesson
    pH=−log⁡[H+]\mathrm{pH} = -\log[\mathrm{H^+}]
  • L42
    Lesson 42
    Concentration from pH
    [H⁺] = 10⁻ᵖᴴ · undoing the logarithm

    Every machine in this room runs backwards.

  • L43
    Lesson 43
    pH plus pOH
    The two-ended ruler

    In any water solution at room temperature the two ends are chained together: pH + pOH = 14 — read aloud: pH plus pOH equals fourteen.

    The formula in this lesson
    pH+pOH=14\mathrm{pH} + \mathrm{pOH} = 14
  • L44
    Lesson 44
    Powers of ten
    one pH unit is a factor of ten — estimate first

    Because pH is a logarithm, its steps do not add — they multiply.

  • L45
    Lesson 45
    Titration
    the burette finds the unknown concentration

    A titration measures a concentration you cannot see by reacting it away with one you know.

    The formula in this lesson
    CaVa=n CbVbC_a V_a = n\,C_b V_b
  • ★
    Boss lesson
    The Litmus Final
    the boss · no calculator · titrate it, then place it on the scale

    No calculator — every concentration is pinned to an exact power of ten, so the logs are mental.

    The formula in this lesson
    CaVa=n CbVbC_a V_a = n\,C_b V_b

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